Material Safety Data Sheet (MSDS) for Block Blue Gel

Identification

Product Name: Block Blue Gel
Product Code: BBG-1123
Recommended Use: Laboratory staining agent for microscopy and electrophoresis applications
Synonyms: Electrophoresis blue gel, Gel block blue stain
Supplier: Innovative Bio-Labs Solutions Corp, 245 Industrial Park Drive, Suite 9, Portland, OR, 97214
Telephone: (503) 555-2654
Email: safety@iblabs.com
Emergency Contact: Chemtrec 1-800-424-9300 (24 hours)
Date of Preparation: June 4, 2024

Hazard Identification

Classification: Eye irritant category 2A, Skin irritant category 2, Not classified for acute toxicity
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, Causes skin irritation, May cause respiratory irritation
Pictograms: Exclamation mark (GHS07)
Precautionary Statements: Avoid breathing vapors, Wear protective gloves and eye protection, Wash thoroughly after handling, Use only in a well-ventilated area, If in eyes: Rinse cautiously with water for several minutes

Composition / Information on Ingredients

Key Ingredients: Triarylmethane blue dye (CAS number: 548-62-9) 3-7%, Polyacrylamide copolymer (CAS number: 9003-05-8) 20-35%, Glycerol (CAS number: 56-81-5) 10-20%, Deionized water 45-60%
Trace Impurities: None expected above 0.1% by weight
Other Components: Proprietary stabilizers under 1%
Impurity Disclosure: Does not contain heavy metals, phenols, or known carcinogens

First Aid Measures

Inhalation: Move affected person to fresh air, keep at rest, get medical attention if symptoms persist
Skin Contact: Wash with soap and plenty of water, remove contaminated clothing, seek medical advice if irritation persists
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, seek medical attention if irritation persists
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical attention
Important Symptoms: Redness, eye watering, itching, mild throat irritation after respiratory exposure

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, carbon dioxide, water spray, or foam
Unsuitable Media: Do not use a direct water jet
Special Hazards: May emit toxic fumes of carbon oxides and nitrogen oxides under combustion
Advice for Firefighters: Wear self-contained breathing apparatus, wear full protective clothing, collect contaminated firewater for disposal
Combustion Products: Carbon monoxide, carbon dioxide, nitrogen compounds, trace blue pigment compounds

Accidental Release Measures

Personal Precautions: Wear chemical-resistant gloves, eye protection, avoid inhaling fumes
Environmental Precautions: Prevent entry into drains, waterways, or soil
Cleanup Methods: Absorb spill with inert material (sand, earth, vermiculite), scoop up and transfer to labeled container, wash spill area thoroughly with water and detergent, ventilate area
Disposal of Cleaned Material: Dispose of as chemical waste according to local regulations

Handling and Storage

Handling: Use in well-ventilated area, keep container tightly closed, avoid direct contact with skin and eyes, do not eat, drink, or smoke while handling
Storage Conditions: Store in a cool, dry, well-ventilated place, out of direct sunlight, store at 4-25°C, keep away from strong oxidizers, acids, and foodstuffs
Packaging: Keep in original sealed containers with proper labeling, store upright

Exposure Controls and Personal Protection

Exposure Limits: No applicable occupational exposure limits for listed ingredients, recommended threshold limit for triarylmethane blue dye: 0.5 mg/m³
Engineering Controls: Use local exhaust ventilation or process enclosures to reduce airborne exposure
Personal Protective Equipment: Chemical-resistant gloves (nitrile or latex), splash-proof goggles or face shield, lab coat or apron, closed-toe shoes
Hygiene Measures: Wash hands and exposed areas with soap and water after use, remove and wash contaminated clothing prior to reuse, do not eat or drink in working area

Physical and Chemical Properties

Physical State: Gel
Color: Deep blue
Odor: Slight, characteristic
pH: 6.5–7.5
Melting Point: Not applicable (gel matrix)
Boiling Point: Approximately 100°C
Flash Point: Not flammable
Solubility: Partially miscible in water
Relative Density: Approximately 1.2 g/cm³
Viscosity: High, semi-solid
Vapor Pressure: Negligible
Evaporation Rate: Not rapid
Explosive Properties: Not expected

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Reactivity: Not classified as reactive
Conditions to Avoid: Excessive heat, freezing temperatures, direct sunlight
Incompatible Materials: Strong oxidizing agents, concentrated acids, and alkalis
Hazardous Decomposition Products: Combustion can produce carbon monoxide, carbon dioxide, nitrogen oxides, minor blue dye byproducts

Toxicological Information

Acute Toxicity: Not orally toxic at typical exposure levels, may cause gastrointestinal discomfort if swallowed
Skin Corrosion/Irritation: Causes mild skin irritation on prolonged contact
Serious Eye Damage/Irritation: Can cause serious eye irritation
Respiratory Sensitization: May cause mild throat and nasal irritation
Germ Cell Mutagenicity: No evidence of mutagenicity in standard laboratory tests
Carcinogenicity: Not classified as carcinogen by IARC or NTP
Reproductive Toxicity: No adverse reproductive effects reported
Target Organ Effects: Eyes, skin, respiratory tract in cases of direct exposure

Ecological Information

Aquatic Toxicity: Not expected to be acutely toxic to aquatic organisms at working concentrations; blue dye component may cause local discoloration
Persistence and Degradability: Partially biodegradable; polymer carrier may persist in soil/water
Bioaccumulative Potential: Not expected to bioaccumulate due to high molecular weight
Mobility in Soil: Low mobility, tends to adhere to soil particles due to gel matrix
Other Adverse Effects: Avoid release to the environment, effects on local water coloration may occur

Disposal Considerations

Waste Disposal Methods: Collect and dispose of in accordance with local, state, and federal regulations, incineration or landfill at approved facilities
Contaminated Packaging: Rinse containers before recycling or disposal, avoid reuse unless properly decontaminated
Special Precautions: Do not permit to enter municipal sewers, storm drains, surface water, or soil

Transport Information

UN Number: Not regulated under UN Model Regulations
Proper Shipping Name: Not dangerous goods
Transport Hazard Class: Not classified
Packing Group: Not applicable
Environmental Hazards: None under current transportation guidelines
Transport in Bulk: Not applicable for product form and scale
Special Precautions: Prevent container rupture or leakage during transport

Regulatory Information

OSHA Hazard Communication Status: Regulated as an irritant chemical
TSCA Inventory: All ingredients present on TSCA Inventory
SARA Title III: Not subject to Section 302, 304, or 313 reporting
California Proposition 65: Product does not contain known listed chemicals
European Regulations: Conforms to REACH as article, not subject to SVHC restrictions
Other Local Regulations: Observe local, region-specific requirements for handling and disposal