MSDS for Fragrant Silica Gel

Identification

Product Name: Fragrant Silica Gel
Product Description: Granular or bead-shaped adsorbent with added fragrance compounds, usually dyed to indicate moisture absorption level
Recommended Uses: Moisture control in packaging, closets, shoes, electronics, and storage spaces
Manufacturer Details: Manufacturer’s address, contact phone, and emergency hotline required for supply chain documentation
Synonyms: Aromatic silicic acid, perfumed desiccant granules
Product Code: Internal SKU or reference based on specific blend or fragrance included
Relevant Identifiers: CAS Number (for pure silica gel: 112926-00-8), batch number for traceability

Hazard Identification

GHS Classification: Not classified as hazardous by GHS; main risks stem from inhaling dust or direct contact with fragrances
Physical Hazards: Rigid granules present a choking risk for children and pets; dust may irritate eyes or respiratory tract
Health Hazards: Silica gel in this application is non-toxic, but ingestion can cause discomfort; added fragrances may trigger allergic reactions or asthma in sensitive individuals
Environment Hazards: Improper disposal may lead to microplastic contamination, potential for adverse impact on wildlife if packets are discarded outside
Precautionary Statements: Keep out of reach of children, avoid inhaling dust or placing in food containers, wash hands after handling

Composition / Information on Ingredients

Synthetic Amorphous Silica: 95-98% by weight, CAS Number 112926-00-8, inert and non-crystalline
Fragrance Compounds: 1-3% by weight, proprietary blend; typical ingredients may include essential oils, aldehydes, or synthetic aromas that are compliant with IFRA safety standards
Dye/Indicator: 0-1% by weight; common dyes include methyl violet or cobalt chloride (blue indicator is less common due to toxicity); orange or green indicators tend to avoid heavy metals
Additives & Fillers: Trace amounts of binders or anti-dusting agents may be present, all ingredients declared below mandatory reporting thresholds

First Aid Measures

Inhalation: Move affected person to fresh air; seek medical attention if persistent coughing or difficulty breathing occurs; provide oxygen support if required
Eye Contact: Rinse with water for several minutes, remove contact lenses if present and easy to do; continue rinsing and seek medical advice if irritation continues
Skin Contact: Brush off particles, wash thoroughly with soap and water; fragrance or dye may cause mild irritation or allergic reaction in some, seek care for rash or discomfort
Ingestion: Rinse mouth and drink water to dilute silica gel; large quantities or packets containing indicator dyes require prompt medical attention; supervise children closely
Symptoms & Effects: Mild irritation to respiratory or gastrointestinal systems, possible allergic reaction due to fragrance content; usually self-limiting with basic care

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide, as appropriate for surrounding fire; silica gel itself does not burn
Hazardous Combustion Products: Fragrance components may release small amounts of irritating or toxic fumes; silica gel is stable at high temperature and decomposes above 1500°C
Equipment: Firefighters should use full protective gear and self-contained breathing apparatus due to possible smoke or chemical fume exposure
Specific Hazards: Material does not support combustion, but packaging and fragrance may add minor flammable components
Special Procedures: Cool any exposed, sealed containers with water spray to prevent rupture; avoid inhaling combustion gases

Accidental Release Measures

Personal Protection: Wear gloves, dust mask, and eye protection when cleaning spilled material, especially indoors
Environmental Controls: Prevent entry into drains or waterways; sweep up granules with minimal dust formation
Cleanup Methods: Use dry sweeping, HEPA vacuum, or damp cloth if necessary; dispose of waste silica gel according to local regulations for chemical or household waste
Precautions for Safe Handling: Ensure good ventilation; clean up promptly to avoid slip risk or unintended exposure to pets and children
Disposal of Contaminated Material: Collect spillage in a labeled container for safe disposal; avoid contaminating compost or food waste streams

Handling and Storage

Handling: Minimize producing dust by handling gently; avoid direct intake near food or beverages; always check manufacturer’s guidance for specific aromatic additives
Storage Conditions: Store in dry area in sealed containers away from moisture; avoid temperature extremes and direct sunlight to prevent degradation of fragrance compounds
Separation: Keep away from strong acids, alkalis, oxidizers, or any incompatible material that could react with additives or dye
Packaging: Resealable packs, tamper-evident sachets, or bulk drums; label storage containers clearly with product name and hazard statements
Special Precautions: Lock storage if children are present; ensure packets do not leak or degrade in packaging environments

Exposure Controls and Personal Protection

Occupational Exposure Limits: Silica gel is not considered hazardous dust at consumer use level; use workplace safety standards for nuisance dust (e.g., OSHA PEL for particulates not otherwise regulated: 15 mg/m³ total, 5 mg/m³ respirable fraction)
Engineering Controls: Use local exhaust ventilation when handling large quantities or manufacturing
Personal Protective Equipment: Gloves recommended for sensitive skin, eye protection for bulk handling, dust mask in poorly ventilated areas
Hygiene Measures: Wash hands after using; avoid touching face or ingesting food before washing
Medical Surveillance: Allergy testing may be advised for people frequently exposed to synthetic fragrances or indicator dyes

Physical and Chemical Properties

Appearance: Transparent or colored beads, granular with added fragrance note
Odor: Clearly defined floral, citrus, or woody aroma depending on formulation
pH: Typically neutral (6.5-7.5 in aqueous suspension)
Melting Point/Freezing Point: Stable up to 1600°C; does not melt or freeze under ordinary conditions
Boiling Point/Range: Not applicable
Vapor Pressure: Not volatile
Solubility: Insoluble in water and most organic solvents
Flash Point: Not applicable; fragrance components may have low flash point but are present in very low concentrations
Other Information: Not hygroscopic after moisture saturation

Stability and Reactivity

Chemical Stability: Stable under normal storage and use conditions
Dangerous Reactions: No dangerous polymerization
Incompatible Materials: Strong acids, bases, or oxidizers may affect dye or fragrance integrity
Hazardous Decomposition Products: At high temperature, can decompose to form silicon dioxide dust; combustion of fragrances and dyes may yield smoke, CO2, and trace volatile organics
Protective Measures: Avoid exposure to high temperatures, open flames, or incompatible chemicals

Toxicological Information

Acute Toxicity: Silica gel considered inert and non-toxic in small doses; fragrances present a mild ingestion risk for children and pets
Skin/Eye Irritation: Dust or fragrance may cause transient irritation; indicator dyes rarely cause lasting injury
Respiratory Sensitization: Fragrance and dust can trigger asthma or allergic response in sensitive individuals
Carcinogenicity: Amorphous silica not regarded as carcinogenic; indicator dyes with cobalt chloride are discouraged for consumer goods because cobalt compounds are suspected carcinogens
Chronic Effects: Frequent exposure to dust or fragrances may cause dermatitis, conjunctivitis, or respiratory symptoms in sensitized individuals

Ecological Information

Ecotoxicity: Bulk silica gel poses little risk to aquatic or land environments, but improper disposal increases microplastic load
Persistence and Degradability: Silica is inorganic and non-biodegradable; fragrance components may degrade in soil but could impact plant or microbial health
Bioaccumulative Potential: Does not accumulate in living organisms; dyes and fragrance compounds could persist temporarily in soil or water
Mobility in Soil: Granules are not mobile, but small beads and powder can enter drainage systems
Other Adverse Effects: Wildlife may ingest packets, so spent gel should not be littered

Disposal Considerations

Waste Treatment Methods: Used or spent gel should be collected and disposed of in solid waste; avoid releasing beads into the environment
Recommended Disposal Container: Sealed, labeled waste containers or municipal trash destined for landfill
Recycling & Reuse: Some municipal programs accept silica gel for reuse in moisture control; do not compost
Sewage Disposal: Never flush packets; granules may clog pipes or interfere with wastewater processing
Regulatory Considerations: Check local regulations on disposal of products containing synthetic fragrances or indicator dyes

Transport Information

UN Number: Not regulated as a hazardous material for ground, air, or sea transport
Transport Hazard Class: Not classified as dangerous goods under international guidelines
Packing Group: Not applicable
Special Precautions for User: Ensure packaging is secure to prevent leaks; label transport containers with producer details
Environmental Hazards: None known for normal handling; avoid spills during bulk transit

Regulatory Information

Labeling Requirements: Safety labeling with warning regarding choking hazard, fragrance sensitivity, and disposal guidance
Safety Data Sheet Compliance: MSDS supplied in accordance with OSHA Hazard Communication Standard and EU REACH requirements
Inventory Status: Silica gel and common fragrance materials appear on most chemical inventories; indicator dyes may be restricted in some jurisdictions
Legal Restrictions: Cobalt-based dyes restricted in toys and consumer goods in many regions; synthetic fragrances conform to IFRA and allergen labeling standards
Other Regulations: Packaging designed to reduce child access under global consumer product safety laws